发明名称 Terphenylene derivative, tetrahaloterphenyl derivative, and processes for producing both
摘要 An object of the present invention relates to provision of a terphenylene derivative having excellent oxidation resistance and capable of forming a semiconductor active phase by a coating process and an oxidation-resistant organic semiconductor material using the same, as well as an organic thin film. The invention relates to production of a terphenylene derivative represented by the formula (1) by tetralithiating a tetrahaloterphenyl derivative with a lithiating agent and subsequently treating the resulting compound with a copper compound: [ka 1] wherein R1 to R14 are the same or different and each represents a hydrogen atom, a fluorine atom, a chlorine atom, an aryl group having 4 to 30 carbon atoms, an alkynyl group having 3 to 20 carbon atoms, an alkenyl group having 2 to 30 carbon atoms, an alkyl group having 1 to 20 carbon atoms or a halogenated alkyl group having 1 to 20 carbon atoms, or a diarylamino group having 8 to carbon atoms; and l, m, and n each represents an integer of 0 or 1.
申请公布号 US7985885(B2) 申请公布日期 2011.07.26
申请号 US20060910759 申请日期 2006.03.28
申请人 TOSOH CORPORATION 发明人 WATANABE MAKOTO;OHASHI TOMOKAZU;YAMAMOTO TOSHIHIDE
分类号 C07C13/465;C07C22/00 主分类号 C07C13/465
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