发明名称 |
Process for the Oxidation of Secondary Amines into the Corresponding Nitroxides |
摘要 |
The invention relates to a process for the preparation of secondary nitroxide radicals from their corresponding secondary amines by oxidation with an organic peracid, comprising the steps a) adding to a reaction vessel a secondary amine, optionally together with an organic solvent and in one batch a base selected from the group consisting of alkali metal, alkaline earth metal or ammonium bicarbonates and alkaline earth metal or ammonium carbonates or mixtures thereof in the form of a solid together with water or as an aqueous slurry; b) dosing a peracid under stirring to the reaction mixture in an amount of 1.0 to 2.5 mol per mol of secondary amine; and c) isolating the organic phase.
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申请公布号 |
US2010305322(A1) |
申请公布日期 |
2010.12.02 |
申请号 |
US20100854677 |
申请日期 |
2010.08.11 |
申请人 |
NESVADBA PETER;BUGNON LUCIENNE;VON BUEREN MARTIN |
发明人 |
NESVADBA PETER;BUGNON LUCIENNE;VON BUEREN MARTIN |
分类号 |
C07D211/44;C07B33/00;C07B43/00;C07B60/00;C07C291/04;C07D211/94;C07D491/113 |
主分类号 |
C07D211/44 |
代理机构 |
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代理人 |
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主权项 |
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地址 |
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