ACTIVATING SUPPORTS WITH CONTROLLED DISTRIBUTION OF OH GROUPS
摘要
The present invention relates to a process for preparing an activating support for metallocene complexes in the polymerisation of olefins comprising the steps of: I) providing a support consisting in particles formed from at least one porous mineral oxide; II) optionally fixing the rate of silanols on the surface of the support; III) functionalising the support with a solution containing a metallic salt; IV) heating the functionalised support of step c) under an inert gas or hydrogen; V) oxidising the support of step IV by treatment under N2O and then under oxygen; Vl) retrieving an active support having a controlled number of OH groups. That activating support is used to activate a metallocene catalyst component for the polymerisation of olefins.
申请公布号
WO2010127988(A1)
申请公布日期
2010.11.11
申请号
WO2010EP55797
申请日期
2010.04.29
申请人
TOTAL PETROCHEMICALS RESEARCH FELUY;CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE (CNRS);PANNIER, GAELLE;BOISSON, CHRISTOPHE;SPITZ, ROGER