摘要 |
A process for polymerizing olefin(s) utilizing a cyclic bridged metallocene catalyst system to produce polymers with improved properties is provided. The catalyst system may include a cyclic bridged metallocene, LA(R'SiR')LBZrQ2, activated by an activator, the activator comprising aluminoxane, a modified aluminoxane, or a mixture thereof, and supported by a support, where: LA and LB are independently an unsubstituted or a substituted cyclopentadienyl ligand bonded to Zr and defined by the formula (C5H4-dRd), where R is hydrogen, a hydrocarbyl substituent, a substituted hydrocarbyl substituent, or a heteroatom substituent, and where d is 0, 1, 2, 3 or 4; LA and LB are connected to one another with a cyclic silicon bridge, R'SiR', where R' are independently hydrocarbyl or substituted hydrocarbyl substituents that are connected with each other to form a silacycle ring; and each Q is a labile hydrocarbyl or a substituted hydrocarbyl ligand. |
申请人 |
UNIVATION TECHNOLOGIES, LLC |
发明人 |
RIX, FRANCIS, C.;LI, DONGMING;LUE, CHING-TAI;KUO, CHI-I;GOODE, MARK, G.;ZILKER, DANIEL, P., JR.;KWALK, TAE, HOON |