| 摘要 |
PURPOSE: A metal-macrocyclic compound complex and a method for manufacturing the same are provided to prevent coagulation and to improve dispersion ability. CONSTITUTION: A method for synthesizing a metal-macrocyclic compound complex comprises: a step of mixing metal salt, macrocyclic compound, and basic solution to make mixture solution; and a step of reacting in the mixture solution. The metal salt is KAuCl4, NaAuCl4·2H2O, HAuCl4·3H2O, NaAuBr4·xH2O(x=1~5), AuCl3, AuBr3, AuCl, AgNO3, AgCl, AgBr, AgI, CH3COOAg or AgBF4. The macrocyclic compound is cucurbituril. The cucurbituril is cucurbit[5]uril cucurbit[6]uril cucurbit[7]uril cucurbit[8]uril cucurbit[10]uril or cucurbit[5]uril. The basic solution is NaOH solution. The reaction is performed at room temperature to 65°C. The metal-macrocyclic compound complex comprises metal particle and macrocyclic compound. The oxidation number of metal particle is 0.
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