| 摘要 |
A method for producing a norbornene derivative wherein,
in the presence of palladium and at least one selected from phosphorus compounds represented by the following General Formulae (1) and (2):
[in Formula (1), R 1 , R 2 , R 3 and R 4 each independently represent a hydrogen atom or the like, and R 5 and R 6 each independently represent a branched chain saturated hydrocarbon group having 3 to 10 carbon atoms or the like], and
[in Formula (2), R 7 represents a branched chain saturated hydrocarbon group having 3 to 10 carbon atoms],
a norbornadiene derivative represented by the following General Formula (3):
[in Formula (3), R 8 , R 9 , R 10 , R 11 and R 12 each independently represent a hydrogen atom or the like, 1 represents an integer of 0 or 1, m represents an integer of 0 or 1, and n represents an integer of 0 or 1], and a bromine compound represented by the following General Formula (4):
€ƒ€ƒ€ƒ€ƒ€ƒ€ƒ€ƒ€ƒ[Chemical Formula 4] Br-Z-R 13 €ƒ€ƒ€ƒ€ƒ€ƒ(4)
[in Formula (4), Z represents a phenylene group or the like, and R 13 represents a hydrogen atom or the like] are reacted with each other, to thereby obtain a norbornene derivative represented by the following General Formula(5):
[in Formula (5), R 14 , R 15 , R 16 , R 17 and R 18 each independently represent a hydrogen atom or the like, Z represents a phenylene group or the like, R 19 represents a hydrogen atom or the like, 1 represents an integer of 0 or 1, m represents an integer of 0 or 1, and n represents an integer of 0 or 1], the norbornene derivative having a configuration of a substituent represented by Z in General Formula (5) that is an exo configuration. |
