发明名称 Alkylidene complexes of ruthenium containing N-heterocyclic carbene ligands; use as highly active, selective catalysts for olefin metathesis
摘要 The invention relates to a complex compound of ruthenium of the general structural formula I in which X1 and X2 may be identical or different and represent an anionic ligand, in which R1 and R2 are identical or different, but may also have a ring, in which R1 and R2 represent hydrogen or/and a hydrocarbon group, in which the ligand L1 is a N-heterocyclic carbene and in which the ligand L2 is a neutral electron donor, especially a N-heterocyclic carbene or an amine, imine, phosphane, phosphite, stibine, arsine, carbonyl compound, carboxyl compound, nitrile, alcohol, ether, thiol or thioether, wherein R1, R2, R3 and R4 represent hydrogen or/and hydrocarbon groups. The invention relates also to a process for the preparation of acyclic olefins having two or more carbon atoms or/and of cyclic olefins having four or more carbon atoms from acyclic olefins having two or more carbon atoms or/and from cyclic olefins having four or more carbon atoms by olefin metathesis reaction in the presence of at least one catalyst, wherein such a complex compound is used as catalyst and wherein R'1, R'2, R'3 and R'4 hydrogen or/and hydrocarbon groups.
申请公布号 US7652145(B2) 申请公布日期 2010.01.26
申请号 US20040021967 申请日期 2004.12.23
申请人 发明人 HERRMANN WOLFGANG ANTON;SCHATTENMANN WOLFGANG;WESKAMP THOMAS
分类号 C07F15/00;B01J31/00;B01J31/22;C07C2/32;C07C67/313;C07C67/475;C08F2/60;C08F4/80;C08G61/06 主分类号 C07F15/00
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