发明名称 |
Processes for the recovery of ruthenium from materials containing ruthenium or ruthenium oxides or from ruthenium-containing noble metal ore concentrates |
摘要 |
Recovery (M1) of ruthenium from materials containing ruthenium or ruthenium oxides or from ruthenium-containing noble metal ore concentrates involves introducing the material into an alkali hydroxide melt in the presence of nitrate as oxidizing agent and forming an oxidized melt residue with water-soluble ruthenate; subjecting the oxidized melt residue to dissolution in water; adding a reducing agent; and precipitating the metals formed. Recovery (M1) of ruthenium from materials containing ruthenium or ruthenium oxides or from ruthenium-containing noble metal ore concentrates involves either: introducing the material into an alkali hydroxide melt in the presence of nitrate as oxidizing agent and forming an oxidized melt residue with water-soluble ruthenate; subjecting the oxidized melt residue to dissolution in water; adding a reducing agent; and precipitating the metals formed; or introducing the material into an alkali hydroxide melt in the presence of nitrate as oxidizing agent to form water-soluble ruthenate; subjecting the oxidized melt residue to dissolution in water to obtain a ruthenate solution; treating the ruthenate-containing solution with an oxidizing agent; distilling off of the ruthenate obtained; and absorbing the ruthenate in hydrochloric acid. An independent claim is included for separation (M2) of selenium from materials containing ruthenium or ruthenium oxides or from ruthenium-containing noble metal ore concentrates involving: introducing the material into the alkali hydroxide melt in the presence of nitrate as oxidizing agent and forming the oxidized melt residue with water-soluble ruthenate; subjecting the oxidized melt residue to dissolution in water, where the solution subsequently contains ruthenate and selenate; adding the reducing agent; precipitating water-containing ruthenium(IV) oxide, where the selenium is dissolved quantitatively in second step as selenate. |
申请公布号 |
ZA200900657(B) |
申请公布日期 |
2009.12.30 |
申请号 |
ZA20090000657 |
申请日期 |
2009.01.28 |
申请人 |
W. C. HERAEUS GMBH. |
发明人 |
GREHL, MATTHIAS;NOWOTTNY, CHRISTIAN;STETTNER, MARTIN;KRALIK, JOACHIM, MEYER, HORST |
分类号 |
C01G;C22B |
主分类号 |
C01G |
代理机构 |
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代理人 |
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主权项 |
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地址 |
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