| 摘要 |
FIELD: chemistry. ^ SUBSTANCE: invention relates to a method of producing new organoaluminium compounds, which can be used as components of catalyst systems in oligomerisation and polymerisation of olefin, diene and acetylene hydrocarbons, as well as in fine organic and organometallic synthesis. A method is described for producing 10-alkyl-12-ethyl-12-aluminabicyclo[7.3.01.9]dodec-1(2)-enes (1), which involves reacting an equimolar mixture of cyclonone-1,2-diene and -olefins with ethylaminium dichloride in the presence of magnesium (powder) and zirconocene dichloride catalyst in an argon atmosphere at room temperature in tetrahydrofuran for 8 to 12 hours. ^ EFFECT: proposed method allows for obtaining a new compound with high regioselectivity and high output 73-87%. ^ 1 cl, 1 tbl, 11 ex |
