发明名称 |
PROCESS FOR THE PREPARATION OF BRANCHED POLYBUTADIENE WITH A HIGH CONTENT OF 1,4-CIS UNITS |
摘要 |
Process for the preparation of polybutadiene effected by the polymerization of butadiene in an aliphatic and/or cyclo-aliphatic solvent in the presence of a catalytic system prepared in situ which comprises: (i) a carboxylate of neodymium soluble in the process solvent containing a variable quantity of water, the H2O/Nd molar ratio ranging from 0.001/1 to 0.50/1; (ii) an alkyl compound of aluminum; (iii) an alkyl compound of aluminum in which at least one bond of Al consists of an Al-Cl bond; The total Al/Nd molar ratio ranging from 4/1 to 12/1, and the Cl/Nd molar ratio ranging from 2/1 to 6/1.
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申请公布号 |
CA2719728(A1) |
申请公布日期 |
2009.10.08 |
申请号 |
CA20092719728 |
申请日期 |
2009.03.19 |
申请人 |
POLIMERI EUROPA S.P.A. |
发明人 |
VIOLA, GIAN TOMMASO;ZINNA, MARIANNA |
分类号 |
C08F4/44;C08F4/54;C08F16/06;C08F36/06 |
主分类号 |
C08F4/44 |
代理机构 |
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代理人 |
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地址 |
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