发明名称 METHOD FOR PRODUCING DIMETHYL TRANS-1,4-CYCLOHEXANEDICARBOXYLATE
摘要 PROBLEM TO BE SOLVED: To provide an industrially highly practical method for producing dimethyl trans-1,4-cyclohexanedicaroxylate which has a high yield and excels in productivity, in the isomerization reaction of the cis form of dimethyl 1,4-cyclohexanedicaroxylate (HDMT) to the trans form. SOLUTION: As the isomerization catalyst, a strongly basic tertiary amine compound is used. The base dissociation constant of the strongly basic tertiary amine compound is preferably not less than 9.0. The strongly basic tertiary amine compound is preferably at least one kind selected from the group consisting of 1,5-diazabicyclo[4,3,0]non-5-ene, 1,8-diazabicyclo[5,4,0]undec-7-ene, and 4-dimethylaminopyridine. COPYRIGHT: (C)2009,JPO&INPIT
申请公布号 JP2009126854(A) 申请公布日期 2009.06.11
申请号 JP20070306479 申请日期 2007.11.27
申请人 IWATANI INDUSTRIAL GASES CORP 发明人 ISHIKAWA ATSUSHI;MOTOYAMA MICHIHIRO
分类号 C07C67/333;C07C69/75 主分类号 C07C67/333
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