| 摘要 |
FIELD: chemistry. ^ SUBSTANCE: invention concerns organic magnesium synthesis, particularly method of obtaining 10,11-dialkyl-9-magnesabicyclo[6.3.0]undeca-1(8),10-dienes. Method involves interaction of equimolar mix of cyclooctine and dialkylacetylene with n-BuMgCl in the presence of zirconocene dichloride catalyst in argon atmosphere at room temperature in diethyl ether for 5-7 hours. ^ EFFECT: obtained organic magnesium compounds can be applied as catalytic system components in polymerisation and oligomerisation processes for olefins and diene hydrocarbons, in fine organic, industrial-scale organic and metal-organic synthesis, and in bioactive medicine synthesis. ^ 1 cl, 1 ex, 1 tbl |
