| 摘要 |
<p>Phosphine together with methane is produced by treating with water the residue produced by extracting aluminium in a converter using the sub-halide process. The residue is passed from converter to treatment zone without intermediate exposure to the atmosphere and the gases evolved are withdrawn from the treatment zone. A suitable apparatus is shown in the Figure where residue from converter 10 is discharged from 22 into an enclosed hammer mill 23, where the residue is comminuted to pass through screen 23-preferably 0.25 inch mesh. From 23 it falls into hopper 27 which narrows to form tube 30 of diameter at least 8 times greater than the maximum diameter of the particles. Tube 30 when filled with particles <PICT:1028375/C1/1> forms a dust seal between the converter 10 and the quench tank 47 and inhibits the passage of gas between them. The particles pass from 30 through conveyer 36 and fall into water contained in tank 47. The temp. of the mix produced is maintained at 30 DEG C. by suitable addition of water by pipe 53 and withdrawal of slurry via pipe 52 into the stripper tank 57 which is supplied with steam by pipe 58 to heat the slurry and drive off all the evolved gases through vent 61. If the residue contains only a slight amount of aluminium, the amount of gas evolved may be only small, and the use of the stripper tank unnecessary. The venting of gases from tank 47 through pipe 54 is subject to the control of system 72, which is set to equalize the pressures between the ends of the dust seal column 31. This serves to reinforce the efficiency of the seal in inhibiting the transfer of gas between the quench tank and the converter. The level of particles in 27 is monitored by sensing device 44 which controls the speed of transporting screw 35 so as to maintain the residue level constant and thus maintain the efficiency of the dust seal. The gases evolved from the treatment zone are usually phosphine and methane produced by the action of water on the AIP and the A13C4 content of the residue. The phosphine may be oxidized to phosphoric acid.</p> |
