发明名称 |
FOERFARANDE FOER FRAMSTAELLNING AV VATTENLOESLIGA AKRYLPOLYMERER. |
摘要 |
A process for preparing particulate water-soluble acrylic polymers, e.g. acrylamide or methacrylamide polymers and cationic acrylic polymers, having a high molecular weight, an excellent water solubility and a uniform particle size with a good productivity, which comprises: (a) adding at least one surfactant selected from the group consisting of a non-ionic surfactant and an anionic surfactant to an at least 20% by weight aqueous solution of a vinyl monomer in an amount of 0.001 to 1% by weight based on the monomer. (b) adjusting the dissolved oxygen in the aqueous monomer solution to at most 1 mg/liter, (c) admixing the aqueous monomer solution with at most 0.03% by weight of a photopolymerization initiator based on the monomer, (d) continuously feeding the aqueous monomer solution in the form of a layer having a thickness of 3 to 10 mm onto a moving support located in an atmosphere containing at most 1% by volume of oxygen, (e) irradiating the layer of the aqueous monomer solution on the moving support with ultraviolet rays having a wavelength of 300 to 450 millimicrons at an intensity of at most 50 W/m2, (f) continuously taking out the produced polymer in the form of a sheet having a thickness of 3 to 10 mm from the moving support, (g) breaking the polymer sheet to cubic pieces of 3 to 10 mm in length of a side by a roller type cutter, (h) pulverizing the cubic pieces to particles having a diameter of 0.3 to 3 mm by a vertical type cutter, and (i) drying the particles with hot air. |
申请公布号 |
FI850794(L) |
申请公布日期 |
1986.06.28 |
申请号 |
FI19850000794 |
申请日期 |
1985.02.27 |
申请人 |
DAI-ICHI KOGYO SEIYAKU CO.LTD. |
发明人 |
YADA, AKIRA;MATSUMOTO, SHUSAKU;SAITO, TAKAO;NISHIYAMA, TADASHI;ADACHI, YOSHITUGU;KAWAMORI, YOSHIHIRO |
分类号 |
C08F2/10;C08F2/48;C08F2/50 |
主分类号 |
C08F2/10 |
代理机构 |
|
代理人 |
|
主权项 |
|
地址 |
|