摘要 |
The present invention relates to a fuel oil additive comprising A) a copolymer of ethylene and from 18 to 35 mol % of at least one acrylic ester or vinyl ester having a C<SUB>1</SUB>-C<SUB>18</SUB>-alkyl radical and a degree of branching of less than 5 CH<SUB>3</SUB>/100 CH<SUB>2 </SUB>groups, and B) a comb polymer comprising structural units formed from B1) at least one olefin as monomer 1, which bears at least one C<SUB>8</SUB>-C<SUB>18</SUB>-alkyl radical on the olefinic double bond, and B2) at least one ethylenically unsaturated dicarboxylic acid as monomer 2, which bears at least one C<SUB>8</SUB>-C<SUB>16</SUB>-alkyl radical bonded via an amide and/or imide group, in which the parameter Q <maths id="MATH-US-00001" num="00001"> <MATH OVERFLOW="SCROLL"> <MROW> <MI>Q</MI> <MO>=</MO> <MROW> <MROW> <MUNDER> <MO>∑</MO> <MI>i</MI> </MUNDER> <MO></MO> <MSTYLE> <mspace width="0.3em" height="0.3ex"/> </MSTYLE> <MO></MO> <MROW> <MSUB> <MI>w</MI> <MROW> <MN>1</MN> <MO></MO> <MI>i</MI> </MROW> </MSUB> <MO>.</MO> <MSUB> <MI>n</MI> <MROW> <MN>1</MN> <MO></MO> <MI>i</MI> </MROW> </MSUB> </MROW> </MROW> <MO>+</MO> <MROW> <MUNDER> <MO>∑</MO> <MI>j</MI> </MUNDER> <MO></MO> <MSTYLE> <mspace width="0.3em" height="0.3ex"/> </MSTYLE> <MO></MO> <MROW> <MSUB> <MI>w</MI> <MROW> <MN>2</MN> <MO></MO> <MI>j</MI> </MROW> </MSUB> <MO>.</MO> <MSUB> <MI>n</MI> <MROW> <MN>2</MN> <MO></MO> <MI>j</MI> </MROW> </MSUB> </MROW> </MROW> </MROW> </MROW> </MATH> </MATHS> in which w<SUB>1 </SUB>is the molar proportion of the individual chain lengths n, in the alkyl radicals of monomer 1, w<SUB>2 </SUB>is the molar proportion of the individual chain lengths n<SUB>2 </SUB>in the alkyl radicals of the amide and/or imide groups of monomer 2, n<SUB>1 </SUB>are the individual chain lengths in the alkyl radicals of monomer 1, n<SUB>2 </SUB>are the individual chain lengths in the alkyl radicals of the amide and/or imide groups of monomer 2, i is the serial variable for the chain lengths in the alkyl radicals of monomer 1, and is the serial variable for the chain lengths in the alkyl radicals of the amide and/or imide groups of monomer 2 assumes values of from 23 to 27.
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