摘要 |
Disclosed is a process for the preparation of alkylene glycols from the corresponding alkylene oxide, such as ethylene glycol from ethylene oxide, in the presence of water, a catalyst and, optionally, carbon dioxide. The catalyst contains an amphoteric compound, such as such as (ethylenedinitrilo) tetraacetic acid (EDTA). These befunctional compounds have both acid and base moieties. Preferably, a compound useful in the present invention forms a buffered solution in water, i.e., the acid and base moieties do not completely disassociate. The pH of the buffered solution should be 2-10, preferably 5-10, more preferably 4-9. A compound useful in the present invention is preferably organic with the base moiety and the acid moiety being separated by one to four carbon atoms.
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