摘要 |
PROBLEM TO BE SOLVED: To provide a method for producing silver sulfonylimidate that enables the silver sulfonylimidate useful as a catalyst for organic synthesis to be industrially produced easily and efficiently. SOLUTION: The production method is characterized by producing silver sulfonylimidate represented by AgN(Rf<SB>1</SB>SO<SB>2</SB>)(Rf<SB>2</SB>SO<SB>2</SB>) by reacting a sulfonylimide compound represented by M[N(Rf<SB>1</SB>SO<SB>2</SB>)(Rf<SB>2</SB>SO<SB>2</SB>)]<SB>x</SB>, [wherein, Rf<SB>1</SB>and Rf<SB>2</SB>are the same or different and indicate any one of a straight chained or branched 1-12C perfluoroalkyl group, a fluoroalkyl group, a fluoroalkenyl group and a fluoroallyl group; M indicates H or Li, Na, K or Cs among alkaline metals of the group Ia of the periodic table and Mg, Ca, Sr or Ba among alkaline earth metals of the group IIa of the periodic table; and x indicates 1 or 2 among positive integers] and an inorganic silver compound in a hydrofluoric acid solution or mixing an aqueous solution in which the above reaction has been performed with a hydrofluoric acid solution. COPYRIGHT: (C)2007,JPO&INPIT
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