New perylenetetracarboxylic acid diimide useful e.g. as fluorescence dye, coloring material, pigments and printing ink for inkjet printers, and for coloring polymers; and in light absorbing systems and fluorescence solar collector

摘要

7,8,15,16-Dibenzo[a,j]perylenetetracarboxylic acid diimide derivatives (A), are new. 7,8,15,16-Dibenzo[a,j]perylenetetracarboxylic acid diimide derivatives (A) of formula (I) or (II), are new. R1>, R2>pseudohalogen, azides, diazo groups, (iso)cyanates, (iso)thiocyanate, hydrazine (optionally substituted by O, S, N, P, alkoxy groups, carboxy groups, alkali metals, B or Al), at least 4C (preferably 6-25C) alkyl or at least 3C (preferably 9-19C) alkyl (where one or more carbon atoms are replaced by cis- or trans-CH=CH- groups, carbonyl groups, N, O, S, Se, Te, Si, acetylenic -Ctriple boundC- groups (preferably 3C alkyl)), cycloalkyl residues with at least 3C (one or more C replaced by carbonyl, N, O, S, Se, Te, Si, cis or trans-CH=CH- group or acetylenic (-Ctriple boundC-) groups) or phenyl (optionally substituted by aromatics with more than 6 carbon atoms e.g. naphthyl or anthracenyl) (one or more carbon is replaced by carbonyl, N, O or S), where one or more H is replaced by alkyl, preferably tert-butyl or isopropyl, anealated benzene rings, halo, pseudohalogen, azides, diazo, (iso)cyanates or (iso)thiocyanate, O, S, N, P, alkoxy, carboxy, OH, alkali metals, B or Al. Independent claims are also included for: (1) the preparation of (I); and (2) a procedure for the production of a colored polymer, comprising dissolving (I) in monomers, preferably methylmethacrylate monomer, polyacrylate, polycarbonate, polystyrene, polyoxymethylene, polyethylene, polypropylene, polyethyleneterephtalate, polytetrafluoroethylene and perfluorinated hydrocarbons, polyamide, polyester, polyether and silicone and followed by polymerizing. [Image].