| 摘要 |
<p>Organosilicon compounds bearing keto or aldehyde groups are easily prepared in high yield by oxidation of a carbinol-functional precursor by an oxidizing agent in the presence of a nitrogen-containing free radical mediator which contains aliphatic, cycloaliphatic, heterocyclic, or aromatic NO—, NOH—, or H—N—OH group. The oxidation may be conventional, i.e. using air, oxygen, or other oxidant, may be electrochemical, or enzymatic.</p> |
