摘要 |
A catalytic complex Formula (I) for use in carbonyiation reactions, wherein: R, R<SUP>1</SUP> and R<SUP>2</SUP> are independently selected from hydrogen, hydroxyl or from optionally substituted alkyl, alkoxy, aikenyi, alkenoxy, aryl, aryloxy, alkaryl, alkaryloxy, alkenaryl, alkenaryloxy, aralkyl, aralkoxy, aralkenyl, aralkenoxy, cycloalkyl, cycloaikyloxy, heteroaryl, heteroaryloxy, heteroaikyl or heteroalkyloxy; n is from 0 to 4; Q is a halide or pseudohalide; D is S, P, N or O; X is oxygen, carbon, carbonyl, imine, benzylamine, or optionally substituted alky!, aikenyi, aryl, alkary!, alkenaryl, aralkyl, aralkenyl, cycloalkyl, heteroaryl, or heteroaikyl; or D and X together form part of a further ring system on the palladacycle. |