发明名称 Method of forming tiny silicon nitride spacer for flash EPROM by fully wet etching technology
摘要 A method of forming very small silicon nitride spacers in split-gate flash EPROMs is disclosed which prevent the occurrence of "write disturb", unwanted reverse tunneling, or erasing. This is accomplished by forming spacers with well-controlled dimensions and well-defined shapes through a judicious use of a fully wet etch technique, including main-etch and over-etch. The use of a phosphoric acid solution in combination with sulfuric acid+hydrogen peroxide widens the process window from a few seconds to several minutes so that the small-dimensioned silicon nitride spacers can be better controlled than it has been possible in the past. In the first embodiment phosphoric solution is used both for main-etch and for over-etch. In the second embodiment, phosphoric solution is used for main-etch only, while the sulfuric+hydrogen peroxide solution is used as an over-etch in forming the tiny silicon nitride spacers of the invention. In the third embodiment, the step of over-etching of the spacers is combined with the step of stripping off of an implant photomask, thus, shortening the manufacturing product cycle.
申请公布号 US6908813(B2) 申请公布日期 2005.06.21
申请号 US20030410121 申请日期 2003.04.09
申请人 TAIWAN SEMICONDUCTOR MANUFACTURING CO., LTD. 发明人 LIU HUNG-HSIN;CHANG KUEI-JEN;HSIEH TSUNG-CHI;HWANG YUAN-KO;CHEN SHIH CHIUNG
分类号 H01L21/28;H01L21/336;(IPC1-7):H01L21/336 主分类号 H01L21/28
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