发明名称 |
METHOD FOR DEHYDRATION REACTION OF HEXANOL |
摘要 |
<p><P>PROBLEM TO BE SOLVED: To provide a new reaction method for carrying out the dehydration reaction or hydration reaction of an organic compound using supercritical water or subcritical water containing carbon dioxide as a reaction medium. <P>SOLUTION: The invention relates to a non-catalytic reaction method of an organic compound characterized by the selective acid-catalyzed dehydration reaction or hydration reaction of the organic compound without adding a strong acid such as sulfuric acid or hydrochloric acid by using supercritical water or subcritical water mixed with a large excess of carbon dioxide as the reaction medium. The acid-catalyzing effect of the supercritical water or subcritical water can be remarkably improved by the reaction method and, for example, the yield is as high as 60% in the case of the reaction to form cyclohexene by the dehydration of cyclohexanol. <P>COPYRIGHT: (C)2005,JPO&NCIPI</p> |
申请公布号 |
JP2005132809(A) |
申请公布日期 |
2005.05.26 |
申请号 |
JP20030373767 |
申请日期 |
2003.10.31 |
申请人 |
NATIONAL INSTITUTE OF ADVANCED INDUSTRIAL & TECHNOLOGY |
发明人 |
IKUSHIMA YUTAKA;ARAI KUNIO;MINAMI KIMITAKA |
分类号 |
B01J3/00;C07B61/00;C07C1/24;C07C13/20;C07C29/04;C07C35/08;(IPC1-7):C07C1/24 |
主分类号 |
B01J3/00 |
代理机构 |
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代理人 |
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主权项 |
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地址 |
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