发明名称 Synthesis of 7-membered carbocyclic compound having diexomethylene groups
摘要 The present invention relates to a synthesis of a 7-membered carbocyclic compound having diexomethylene groups, more particularly to a synthesis of a 7-membered carbocyclic compound having diexomethylene groups, a novel compound having the structure represented by the following Chemical Formula 1, from trimethylsilanylmethyl-allenol derivative by the intramolecular Prins cyclization using Lewis acid. The 7-membered carbocyclic compound is a useful intermediate for synthesis of other multicyclic compounds. In Chemical Formula 1, R<1 >is a C1 to C6 alkyl group, and R<2 >and R<3 >is respectively a hydrogen atom, or R<1>, R<2 >and R<3 >may be connected with neighboring substituents to form a 5 to 10-membered aliphatic or aromatic ring.
申请公布号 US2005059832(A1) 申请公布日期 2005.03.17
申请号 US20040823707 申请日期 2004.04.14
申请人 KOREA INSTITUTE OF SCIENCE AND TECHNOLOGY 发明人 CHO YONG SEO;CHANG MOON HO;KOH HUN YEONG;PAE AE NIM;KANG HYUN JUNG
分类号 C07B61/00;C07D493/08;(IPC1-7):C07D493/04 主分类号 C07B61/00
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