发明名称 Process for producing fluorinated alcohol
摘要 A method for producing fluorinated alcohols from fluorinated alkyl halides can produce fluorinated alcohols at high product yield and at high selectivity in a single-step reaction. The method eliminates the need to use heavy metals and other toxic compounds that are difficult to handle or process. Specifically, the method produces a fluorinated alcohol represented by the following general formula (2): Rf(A)OH (2) wherein Rf represents a perfluoroalkyl group having 1 to 10 carbon atoms; and A represents a straight-chained or branched saturated hydrocarbon group having 3 to 10 carbon atoms. The method is characterized in that it allows a fluorinated alkyl halide represented by the following general formula (1) to react with an alkali metal salt of 4-hydroxybutyrate in a gamma-butyrolactone solvent: Rf(A)X (1) wherein Rf and A are as defined above; and X represents a halogen atom.
申请公布号 US2004152926(A1) 申请公布日期 2004.08.05
申请号 US20040476540 申请日期 2004.03.01
申请人 MIMURA HIDEYUKI;KAWADA KOSUKE;ARAI SHOJI 发明人 MIMURA HIDEYUKI;KAWADA KOSUKE;ARAI SHOJI
分类号 C07C29/124;C07C31/38;C07C31/42;C07C31/44;C07C205/43;C07C233/10;C07C233/28;C07C233/33;C07C233/44;C07C233/55;C07F9/12;(IPC1-7):C07C31/34 主分类号 C07C29/124
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