发明名称 |
Verfahren zur Herstellung von Dihydrocitral |
摘要 |
The preparation of dihydrocitral (I) by rearrangement of dihydrodehydrolinalool (II) is catalyzed by a combination of a molybdenum compound (III) and a sulfoxide (IV), in presence of an organic acid. The preparation of dihydrocitral of formula (I) by rearrangement of dihydrodehydrolinalool of formula (II) is effected in aprotic organic solvent, in presence of an organic acid of pK 4.0-6.5, using a catalyst system consisting of a molybdenum compound of formula MoO2X2 (III) (X = acetylacetone or halide ion) and a dialkyl or diaryl sulfoxide (IV). |
申请公布号 |
DE59908545(D1) |
申请公布日期 |
2004.03.25 |
申请号 |
DE1999508545 |
申请日期 |
1999.03.30 |
申请人 |
F. HOFFMANN-LA ROCHE AG, BASEL |
发明人 |
BONRATH, WERNER |
分类号 |
B01J31/20;C07B61/00;C07C45/51;C07C47/21;(IPC1-7):C07C47/21 |
主分类号 |
B01J31/20 |
代理机构 |
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代理人 |
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主权项 |
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地址 |
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