摘要 |
<p>Chromatographic separating material comprises (A) a modified calixresorcinarene, with resorcinol hydroxyl groups converted to ether, ester or amide groups and rings are linked by mono- or di((hetero)cyclo)-alkyl- or (hetero)aryl-methylene groups with multiple bond(s), bound covalently to (B) a carrier material containing silanol groups or polymers on the surface. Chromatographic separating material comprises (A) a modified calixresorcinarene of formula (I), bound covalently to (B) a carrier material containing silanol groups or polymer with surface functions of hydroxy-, mercapto-, amino-, carboxy-, isocyanato- or epoxy-alkyl or -alkoxy-silyl, or a group formula (B-1). [Image] A : -OR, -OCH2OR, -OC(O)OR or -OC(O)NHR; B : H, -OR*, Cl, F, Br, I, -CH3, -SO3, -NO2, -NR*2 or -NHR*3+>; C : H, R**, -OR**, -SR**, -NR**2 or -NR**3+>; D : -CR***2 or -CHR***; R, R*, R**, R*** : (un)saturated (cyclo)alkyl containing heteroatom(s) or (hetero)aryl, optionally substituted or condensed with (un)saturated) alkyl and/or aryl, optionally containing heteroatoms, in which R*** must contain double bond(s); n : 3-10; R' : 1-20 C alkyl or alkoxy; X : 1-20 C alkoxy or arylalkoxy in at least one case, otherwise 1-20 C alkyl; Y : -OH, -SH, -NH2, -COOH, -NCO or epoxy.</p> |