发明名称 METHOD FOR PRODUCING AROMATIC AND HETEROAROMATIC CARBOXYLIC ACID BY CATALITIC OZONOLYSIS
摘要 PROBLEM TO BE SOLVED: To provide a method for producing a desired aromatic or heteroaromatic carboxylic acid in higheryield and suppressing byproduct amount very low under easy process conditions. SOLUTION: This method comprises catalytically oxidizing an alkylaromatic compound to obtain the corresponding aromatic or heteroaromatic carboxylic acid. The method also comprises oxidizing the alkylaromatic compound with ozone to obtain the corresponding carboxylic acid in a solvent at a temperature of -70°C to 110°C in the presence of a transition metal catalyst and, if necessary, an acid and, then, isolating the obtained carboxylic acid, wherein the solvent is selected from a group consisting of 1-6C mono- or dicarboxylic acids, esters, water, halogenated hydrocarbons, acetonitrile, 1-6C alcohols, silicones, silicone oils, chemically inactive high-boiling solvents and mixtures of two or more of these solvents. COPYRIGHT: (C)2004,JPO
申请公布号 JP2003335724(A) 申请公布日期 2003.11.28
申请号 JP20030135994 申请日期 2003.05.14
申请人 DSM FINE CHEMICALS AUSTRIA NACHFOLGER GMBH & CO KG 发明人 JARY WALTHER;POECHLAUER PETER;GANGLEBERGER THORSTEN
分类号 C07B61/00;C07C51/34;C07C63/04;C07C63/10;C07D213/55;C07D213/79;C07D213/803;C07D213/807;C07D233/64;(IPC1-7):C07C51/34 主分类号 C07B61/00
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