发明名称 |
One-pot synthesis of group 8 transition metal carbene complexes useful as olefin metathesis catalysts |
摘要 |
The invention provides a novel method for synthesizing transition metal carbene complexes useful as olefin metathesis catalysts. The method is a convenient one-pot synthesis in which transition metal carbenes are prepared in high yield from readily available starting materials via a dihydrogen complex containing two different anionic ligands, preferably a phosphine and a heteroatom-stabilized carbene. The invention additionally provides a method for synthesizing precursors to carbene ligands useful, inter alia, in the aforementioned one-pot synthesis. The precursors are in the form of trichloromethyl adducts of the formula L1-CCl3, where L1 is a heteroatom-stabilized carbene ligand, and are prepared by contacting an unsaturated, ionized analog of L-CCl3 with a non-nucleophilic base in the presence of chloroform.
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申请公布号 |
US6613910(B2) |
申请公布日期 |
2003.09.02 |
申请号 |
US20020115581 |
申请日期 |
2002.04.02 |
申请人 |
CALIFORNIA INSTITUTE OF TECHNOLOGY |
发明人 |
GRUBBS ROBERT H.;MORGAN JOHN P.;BENITEZ DIEGO;LOUIE JANIS |
分类号 |
B01J23/46;B01J31/18;B01J31/22;B01J31/24;C07C6/04;C07C6/06;C07F15/00;C08G61/06;(IPC1-7):C07F15/00;C07F9/02;C07D233/00 |
主分类号 |
B01J23/46 |
代理机构 |
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代理人 |
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主权项 |
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地址 |
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