发明名称 Use of 2,2,6,6 tetraalkylpiperidine-N-oxyl radicals having long alkyl chains as polymerization regulators
摘要 The present invention relates to a polymerizable composition, comprising a) at least one ethylenically unsaturated monomer or oligomer, b) a radical source capable of starting polymerization of the ethylenically unsaturated monomer or oligomer and c) at least one compound of formula (I), wherein n is 1 or 2; R3, R4, R9, R10 are each independently of one another C1-C18alkyl, C2-C18alkenyl or C2-C18alkinyl; or R3 and R4 and/or R9 and R10 form together with the linking carbon atom a C3-C12cycloakyl radical; R5, R6, R7, R8 are each independently of one another hydrogen, C1-C18alkyl, C2-C18alkenyl or C2C18alkinyl; X is -O-, -O-C(O)-, -NR2- or -NR2-C(O)-; R2 is hydrogen, C1-C18alkyl or phenyl; if n is 1, R1 is C8-C36alkyl, C8-C36alkenyl or C8-C36alkinyl; if n is 2, R1 is C10-C36alkylen, C10-C36alkenylen or C10-C36alkinylen. Further objects of the present invention are a process for polymerization and the use of compounds of formula (I) for the polymerization of ethylenically unsaturated monomers.
申请公布号 US6569940(B1) 申请公布日期 2003.05.27
申请号 US20000720440 申请日期 2000.12.22
申请人 CIBA SPECIALTY CHEMICALS CORPORATION 发明人 WUNDERLICH WIEBKE;CLAUSS MARGOT;ROTH MICHAEL;FUSO FRANCESCO
分类号 C08F2/02;C08F2/14;C08F2/16;C08F2/38;C08F4/00;(IPC1-7):C07D251/06;C08K5/349 主分类号 C08F2/02
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