摘要 |
The present invention relates to a process for preparing (cyclo)aliphatic diisocyanates and triisocyanates corresponding to the formula <paragraph lvl="0"><in-line-formula>R-(NCO)n (I), </in-line-formula>wherein R represents a (cyclo)aliphatic hydrocarbon group having up to 15 carbon atoms, provided that there are at least two carbon atoms between two nitrogens, n represents the number 2 or 3, by a) separately heating phosgene and a diamine or triamine corresponding to the formula <paragraph lvl="0"><in-line-formula>R-(NH2)n (II), </in-line-formula>to a temperature of 200° C. to 600° C., wherein the amine may optionally be diluted with an inert gas or with the vapors of an inert solvent, b) optionally passing the reactants over torque-producing baffles and c) continuously reacting phosgene and the amine in the gas phase in a reaction chamber without moving parts and with constrictions of the walls in the region of the reaction zone.
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