发明名称 METHOD OF SEPARATION OF PARAXYLENE INCLUDING ADSORPTION STAGE WITH INJECTION OF WATER AND CRYSTALLIZATION STAGE
摘要 FIELD: separation of paraxylene from starting raw material containing mixture of aromatic C8 isomers. SUBSTANCE: method includes adsorption and desorption stage of isomers of mixture in fluidized layer in at least one column containing zeolite with the use of desorbent. Adsorption and desorption are performed under conditions suitable for obtaining paraxylene enriched fraction and paraxylene depleted fraction. Method includes additionally one crystallization stage of paraxylene enriched fraction at obtaining pure paraxylene. According to invention water is introduced into starting raw material, desorbent and/or recirculating flow circulating between last and first layers of said column at such flow rate that average weight content of water in paraxylene enriched fraction and in paraxylene depleted fraction should range from 1 to 250 h/mln, mainly, from 3 to 120 h/mln. S/F ratio of flow rates of desorbent and starting raw material and desorption stage should be 6-2.5, mainly, 0.8-1.5 and preferably between 1 and 1.35. EFFECT: enhanced efficiency. 21 cl, 9 dwg, 1 tbl, 9 ex
申请公布号 RU2193021(C2) 申请公布日期 2002.11.20
申请号 RU19990116046 申请日期 1997.12.16
申请人 EHNSTITJU FRANSEH DJU PETROL' 发明人 OT'E ZHERAR;METIV'E ALAN;PJUSSI ANNIK
分类号 C07C7/00;C07C7/13;C07C7/14;C07C15/08;(IPC1-7):C07C15/08 主分类号 C07C7/00
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