发明名称 Nmr of solvents using nitroxides to increase
摘要 The solvent contains a hydrogenated free radical (I) with unpaired electrons, where (I) contains a nitroxide radical having N bonded to 2C atoms each bonded to 3 other C atoms and most of the H atoms of (I) consisting of nucleii of deuterium. (I) is pref. ditertio butylnitroxide, triacetoamine nitroxide or 2,2,6,6-tetramethyl-1-aza- 3-cyclohexanone-1-nitroxide. The solvent is pref. e.g. CH3OH, C2H5OH, CH3OCH2CH2OCH3 or their mixtures. A magnetometer is used for measuring weak fields e.g. terrestrial. - Use of deuterium replacing hydrogen in (I) gives finer electronic paramagnetic resonance lines.
申请公布号 CH530645(A) 申请公布日期 1972.11.15
申请号 CH19700014684 申请日期 1970.10.05
申请人 COMMISSARIAT A L'ENERGIE ATOMIQUE 发明人 CHIARELLI,ROBERT;RASSAT,ANDRE
分类号 G01R33/24;(IPC1-7):G01V3/14 主分类号 G01R33/24
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