发明名称 Liquid, radiation-curable composition, especially for producing cured articles by stereolithography having heat deflection temperatures
摘要 The present invention relates to novel resin compositions containing at least one solid or liquid actinic radiation-curable and cationically polymerizable organic substance, an actinic radiation-sensitive initiator for cationic polymerization, an actinic radiation-curable and radical-polymerizable organic substance and an actinic radiation-sensitive initiator for radical polymerization. The actinic radiation-curable and cationically polymerizable organic substance is at least one glycidylether of a polyhydric aliphatic, alicyclic or aromatic alcohol having at least three epoxy groups with epoxy equivalent weight between 90 and 800 grams per equivalent, at least one solid or liquid alicyclic epoxide with an epoxy equivalent weight between 90 and 330 grams per equivalent having at least two epoxy groups and monomer purity greater than about 90% by weight, or at least a solid or liquid epoxycresol novolac or epoxyphenol novolac having epoxy equivalent weight between 130 and 350, or mixtures thereof. The use of the above-mentioned cationically polymerizable components substantially increases the heat deflection temperature of the cured articles while maintaining high photospeed, accuracy, wetting-recoatability, water resistance and good side wall finish. The present invention further relates to a method of producing a cured product, particularly a three-dimensional article, in which a compositions described above are treated with actinic radiation.
申请公布号 US6413696(B1) 申请公布日期 2002.07.02
申请号 US20000602172 申请日期 2000.06.22
申请人 VANTICO INC. 发明人 PANG THOMAS H.;MELISARIS ANASTASIOS P.;RENYI WANG;FONG JOHN W.
分类号 B29C67/00;C08G59/14;C08G59/20;C08G59/68;G03F7/00;G03F7/038;(IPC1-7):G03F7/029;G03F7/027 主分类号 B29C67/00
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