发明名称 Organometallic monoacylarylphosphines
摘要 Compounds of the formula IR1 and R2 independently of one another are C1-C20alkyl, OR11, CF3 or halogen; R3, R4 and R5 independently of one another are hydrogen, C1-C20alkyl, OR1 or halogen; R6, R7, R8, R9 and R10 independently of one another are hydrogen, C1-C20alkyl; C2-C20alkyl which is interrupted once or more than once by nonconsecutive O atoms and which is unsubstituted or substituted by OH and/or SH; or R6, R7, R8, R9 and R10 are OR11, SR11, N(R12)(R13), phenyl or halogen; R11 is C1-C20alkyl, C3-C8cycloalkyl, phenyl, benzyl or C2-C20alkyl which is interrupted once or more than once by O or S and which is unsubstituted or substituted by OH and/or SH; R12 and R13 independently of one another are hydrogen, C1-C20alkyl, C3-C8cycloalkyl, phenyl, benzyl or C2-C20alkyl which is interrupted once or more than once by nonconsecutive O atoms and which is unsubstituted or substituted by OH and/or SH; or R12 and R13 together are C3-C5alkylene which can be interrupted by O, S or NR14; R14 is hydrogen, phenyl, C1-C12alkyl or C2-C12alkyl which is interrupted once or more than once by O or S and which is unsubstituted or substituted by OH and/or SH; and M is hydrogen, Li, Na or K; are valuable intermediates for the preparation of unsymmetrical bisacylphosphine oxides and monoacylphosphine oxides.
申请公布号 US6399805(B2) 申请公布日期 2002.06.04
申请号 US20010776657 申请日期 2001.02.05
申请人 CIBA SPECIALTY CHEMICALS CORPORATION 发明人 WOLF JEAN-PIERRE;AEBLI BEAT MICHAEL;HUG GEBHARD
分类号 G03F7/031;A61K6/00;C07F9/28;C07F9/50;C07F9/53;C07F9/6521;C07F9/6553;C07F19/00;C08F2/46;C08F2/50;C09D4/00;C09D11/10;G03F7/004;G03F7/029;G03F7/038;G03F7/075;(IPC1-7):C07F9/53 主分类号 G03F7/031
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