RUTHENIUM COMPLEXES CONTAINING CARBOIDS

摘要

In ruthenium complexes of general formula A or B, X<1>, X<2> independently represent single or multidentate anionic ligands; R, R', R'' independently represent hydrogen or optionally substituted C1-20-alkyl, C6-20-aryl or C7-20-alkylaryl radicals; and L<1>, L<2> independently represent neutral electron donor ligands which are co-ordinated at the metallic centre as carboids, and which can be linked by a bridge W having 0 to 20 carbon atoms. Said bridge can be a constituent of a cyclic or aromatic group and can be split by heteroatoms, with the exception of C,N-heterocyclic five-membered ring systems.