发明名称 PROCESS FOR THE PRODUCTION OF ESTERS FROM ALCOHOLS USING ACETIC ACID AS ACETYLATING AGENT AND CLAYS AS CATALYSTS
摘要 The present invention relates to a process for the preparation of esters from alcohols using acetic acid as acetylating agent and clays as catalysts, which comprises the preparation of esters in a single step from the reaction of aliphatic, acyclic, cyclic, heterocyclic, alpha,beta-unsaturated and aromatic alcohols with carbon atoms in the range of C1 to C10 with acetic acid in a molar ratio of 1:3 to 11 using reusable natural montmorillonite/metal ion-exchanged clay catalysts in the solvent medium of aliphatic, aromatic, or chlorinated hydrocarbons at 30-140° C. for a period in the range of 0.02 to 3.0 hrs, and recovering the corresponding esters by simple work-up procedure.
申请公布号 US2001016666(A1) 申请公布日期 2001.08.23
申请号 US19990250385 申请日期 1999.02.12
申请人 CHOUDARY BOYAPATI MANORANJAN;BHASKAR VELDURTHY;KANTAM MANNEPALLI LAKSHMI;RAO KOTTAPALLI KOTESWARA;RAGHAVAN KONDAPURAM 发明人 CHOUDARY BOYAPATI MANORANJAN;BHASKAR VELDURTHY;KANTAM MANNEPALLI LAKSHMI;RAO KOTTAPALLI KOTESWARA;RAGHAVAN KONDAPURAM
分类号 B01J21/16;B01J37/30;C07B61/00;C07C67/08;C07C69/14;C07C69/157;(IPC1-7):C07C69/12;C07C51/16 主分类号 B01J21/16
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