(A) Cpds:- W = NO2, CN, H, or Ph P = H or NO2, with the proviso that at least one of W and P = NO2 Q = alkylene, alkenylene, aralkylene, or alkylidene R = alky

摘要

(A) Cpds. (I) W = NO2, CN, H, or Ph P = H or NO2, with the proviso that at least one of W and P = NO2 Q = alkylene, alkenylene, aralkylene, or alkylidene R = alkyl opt. subst. by oxo, alkenyl, acyl-O-, alkyl-O-, aralkyl-O-, aryl-O-, alkyl-OCO-, aralkyl-O-CO, CO2H, carbamoyloxy, Opt. subst. carbamoyl, opt. subst. CONH2, opt. subst. aryl, OH, halogen, SH, S-alkyl, S-aralkyl, S-aryl, alkyl-SO-, aralkyl-SO-, aryl-SO-, alkyl-SO2, aralkyl-SO2, aryl-SO2, heteroalkyl, NH2, NHalkyl, or N(alkyl)2; opt. subst. aryl, or -CH2CH2- linking N to the residue Q. T = a halocarbonate, halothiocarbonate, -CN, -SCN, carbamoyloxy, carbamoylthio, thionocarbamoyloxy, thionocarbamoylthio, pseudo-ureido, pseudo-thioureido, and their N- and N,N-substd. derivs. or a residue of formula- A = O or S M = O, S, NH, or N-alkyl, R3 and R4 = H, alkyl, opt. subst. by halogen, OH, alkoxy, aralkoxy, aryloxy, carbalkoxy, carbaralkoxy, oxo, acyloxy, SH, alkyl-S-, aralkyl-S-, aryl-S-, alkyl-SO, aralkyl-SO, aryl-SO, alkyl-SO2, aralkyl-SO2, aryl-SO2, opt. subst. carbamoyloxy, opt. subst. carbamoyl, opt. subst. sulphamoyl, opt. subst. thiocarbamoyl, opt. subst. dithiocarbamoyl, opt. subst. NH2 or heteroalkyl; opt. subst. aryl; acyl or derivs. such as cyanoacyl, chlorosulphonyl, dichlorophosphoryl; opt. subst. OH; opt. subst. NH2; opt. subst. carbamoyl; opt. subst. thiocarbamoyl; opt. subst. sulphamoyl; opt. subst. alkylidene; opt. subst. aralkylidene, heterocyclic alkylcarbonyl; and/or NO2, with the proviso that if R3 and R4 are linked directly, R3 and R4 = -(CH2)2R5(CH2)2-, where R5 = O, S, CH2, NH, N-alkyl, or a single C-C bond. Y = a bonding residue, e.g. -(CH2)n- where n = 2 or 3. (B) Acid addn. salts of (I).