发明名称 |
método de preparação de ésteres cílicos a partir de compostos com cinco ou seis carbonos que compreende o contato de um leito que contém um catalisador ácido sólido com pelo menos um dentre um composto com cinco ou seis carbonos e método de preparação de ésteres cíclicos com compostos com cinco ou seis carbonos que compreende, irradiando com micro-ondas, uma mistura líquida de um catalisador ácido inorgânico, ácido orgânico e pelo menos um composto com cinco ou seis carbonos |
摘要 |
Described herein are improved methods for the preparation of 5- and 6-membered cyclic mono and diesters of sugar alcohols and anhydrosugar alcohols by reaction with an organic acid RCOOH over a solid acidic substrate. The process is adaptable to a continuous process for simultaneously making and separating the cyclic esters from the sugar alcohols and anhydrosugar alcohols under mild conditions using the solid acid substrate as both the catalyst and a chromatographic bed for separation. The reactions are performed at mild temperatures of 70° C. to 100° C. and the formation of the cyclic esters is nearly quantitative. Also described is a method for making 5- and 6-membered cyclic mono and diesters of sugar alcohols and anhydrosugar alcohols using microwave irradiation in the presence of the organic acid. |
申请公布号 |
BRPI0909576(A2) |
申请公布日期 |
2016.09.20 |
申请号 |
BR2009PI09576 |
申请日期 |
2009.05.28 |
申请人 |
ARCHER DANIELS MIDLAND COMPANY |
发明人 |
ALEXANDRA SANBORN;STEPHEN HOWARD |
分类号 |
C07D493/02;C07D493/04;C07D493/22 |
主分类号 |
C07D493/02 |
代理机构 |
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代理人 |
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主权项 |
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地址 |
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