发明名称 PRODUCTION OF PROPYLATED AROMATIC HYDROCARBON
摘要 PROBLEM TO BE SOLVED: To obtain the subject compound in high yield by reacting an aromatic hydrocarbon with propylene in the presence of a strongly acidic solid catalyst. SOLUTION: This method reacts, in the presence of (A) a strongly acidic solid catalyst, preferably (i) zirconia carrying sulfate group, (ii) titania carrying sulfate group, (iii) zirconia carrying tungsten oxide, (iv) titania carrying tungsten oxide, or (v) perfluoroalkyl sulfonate resin, (B) an aromatic compound, e.g. benzene or toluene with (C) propylene, preferably at 100 to 350 deg.C and 1 to 50 atm. It is preferable, when the component B is benzene, that the component B/component C molar ratio is set at (1:1) to (5:1). The component (i) for the component A is obtained by firing zirconium hydroxide in the air after diluted sulfuric acid is passed therethrough, and the component (v) is obtained by copolymerizing perfluoroepoxide and vinyl sulfonate.
申请公布号 JP2000309547(A) 申请公布日期 2000.11.07
申请号 JP19990120730 申请日期 1999.04.27
申请人 MITSUI CHEMICALS INC 发明人 OOMATSUZAWA TAKESHI;KURANO YOSHITO;TAKAI TOSHIHIRO
分类号 B01J23/30;B01J27/053;C07B61/00;C07C2/66;C07C2/70;C07C15/02;C07C15/085;(IPC1-7):C07C2/70 主分类号 B01J23/30
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