发明名称 THIOETHER COMPOUND, LIQUID CRYSTAL COMPOSITION AND LIQUID CRYSTAL DISPLAY ELEMENT HAVING NEGATIVE VALUE OF PERMITTIVITY ANISOTROPY
摘要 PROBLEM TO BE SOLVED: To obtain a new compound having not only the large absolute value of a negative value of permittivity anisotropy but also a proper value of refractive index anisotropy, good compatibility and high chemical and physical stabilities and useful as a liquid crystal display element. SOLUTION: This compound is represented by formula I [R1 and R2 are each a 1-5C (substituted) alkyl, rings A1 and A2 are each trans-1,4-cyclohexylene, 1,4-cyclohexenylene, or the like; X is CH2S, or the like; (m) is 0 or 1], e.g. trans, trans-4-(2,3-difluoro-4-ethoxyphenylmercaptomethyl)-4'-n- propylbicyclohexane. Furthermore, the above compound is obtained by subjecting a methyl 4'-substituted bicyclohexane-4-carboxylate represented by formula II (Q1 is a 1-15C alkyl or a 1-15C alkoxy group) to reduction with lithium aluminum hydride, reacting the prepared compound with hydrogen bromide and then reacting the resultant 4'-substituted bicyclohexylmethyl bromide with a substituted phenyl mercaptan compound.
申请公布号 JP2000256307(A) 申请公布日期 2000.09.19
申请号 JP19990062223 申请日期 1999.03.09
申请人 CHISSO CORP 发明人 INAGAKI JUNICHI;HARUFUJI TATSUJI;KOIZUMI YASUYUKI;INOUE HIROMICHI;SAITO HIDEO
分类号 C07C323/09;C07C323/12;C07C323/16;C07C323/17;C07C323/20;C09K19/28;C09K19/30;C09K19/42;C09K19/44;C09K19/46;G02F1/13;(IPC1-7):C07C323/09 主分类号 C07C323/09
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