Adhesive sheets or tapes

摘要

A normally tacky adhesive sheet or tape which normally becomes statically charged upon unwinding has a thin flexible permanent conductive coating covering and firmly bonded to at least one of its longitudinal side edges, which conductive coating remains in position and substantially reduces static charging of the sheet or tape when the sheet or tape is unrolled in an atmosphere having a relative humidity of at least 25%. The conductive coating may be of a soft plastic or waxy composition comprising an ionic compound which is capable of providing adequate ionic antistatic conductivity. The conductive coating may comprise a water-soluble hydrophilic quaternary ammonium compound capable of providing adequate antistatic conductivity and which may have the formula where R is a long alkyl group containing at least 12 carbon atoms; R/sv is a short alkylene bridging group; each R/yF is an alkyl or hydrooxyalkyl group having 1 to 3 carbon atoms, with the proviso that at least one R/yF must be hydroxyalkyl; and Y is an anion. R may be the alkyl chain of a fatty acid. R/sv may be a short alkylene bridging group containing 2 or more -CH2- groups. Y may be Cl, Br or NO3. The conductive coating may comprise stearamido propyldimethylbeta -hydroxyethyl ammonium nitrate having the formula The nitrate may be diluted with methyl, ethyl or isopropyl alcohol, water, or a mixture thereof before being applied to the sheet or tape. The nitrate may be diluted with water to a 20% solids concentration before being applied to the sheet or tape. The conductive coating may be a blend of a water-soluble organic polymer, e.g. polyvinyl alcohol, a non-volatile humectant softener, e.g. polypropylene glycol and a soluble ionogen, e.g. lithium chloride. The conductive coating may comprise a conductive metal or carbon black. The adhesive sheet or tape may comprise a layer of adhesive on a thin hydrophobic backing film. The backing film may be electrically or chemically primed to increase the firmness of bonding of the subsequently applied adhesive coating. The backing film which may be transparent or opaque, may be a plasticized cellulose acetate film, a tensilized polyester film, a polyvinyl chloride, polyethylene, polypropylene, polytetrafluoroethylene, or a polychlorotrifluoroethylene film. The backing film may have a primer coating between the film and the adhesive. The film may have a low-adhesion backsize coating thereon. The adhesive sheet or tape may have a width of 1/4 to 48 inches; tape having a width of 1/4 to 1 inch may have the conductive coating on one edge only; tape having a width of 1/4 to 6 inches may have the conductive coating on both edges. The conductive coating may be formed by transfer coating, brushing, padding or spraying the sides of wound rolls of adhesive tape. Examples of primer, adhesive and backsize coatings are given.