摘要 |
PROBLEM TO BE SOLVED: To provide a method for producing a phosphoric ester containing small amount of a pyrophosphate form, from a hydroxy compound having a carboxylic ester or amide, and a polymerizable carbon-carbon double bond. SOLUTION: A compound of formula I (X is O or NH; R1 is H or methyl; R2 is a 1-40C divalent hydrocarbon or the like) is reacted with a phosphorus oxyhalide in the presence of an amine, and a halogen-oxoate of an amine as a by-product is removed from the reaction system. The obtained product is hydrolyzed to provide the objective phosphoric ester of formula III having <=5 wt.% content of a compound of formula IV.
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