发明名称 Process for the preparation of 2-(6-substituted pyrid-2-yloxymethyl) phenylacetate
摘要 PCT No. PCT/GB96/01311 Sec. 371 Date Dec. 2, 1997 Sec. 102(e) Date Dec. 2, 1997 PCT Filed Jun. 3, 1996 PCT Pub. No. WO97/01538 PCT Pub. Date Jan. 16, 1997A process for preparing 2-(6-substituted pyrid-2-yloxymethyl)phenyacetates especially useful as intermediates for producing agricultural fungicides. The invention provides a compound having the formula (I): wherein A and D are independently selected from the group comprising halo, hydroxy, halo(C1-4)alkyl, C1-4alkoxy, thio(C1-4)alkoxy, halo(C1-4)alkoxy, phenyl, phenoxy, nitro, amino, aclyamino, cyano, carboxy, C1-4 alkoxycarbonyl and C1-4 alkylcarbonyloxy, or D is C1-4 alkyl, and m is 0 or an integer of from 1 to 3. The process comprises treating a compound of formula (II): wherein A, D and m are defined as above and M is a metal atom, with a compound of formula (III): wherein L is a leaving group.
申请公布号 US6015905(A) 申请公布日期 2000.01.18
申请号 US19970973252 申请日期 1997.12.02
申请人 ZENECA LIMITED 发明人 RITCHIE, DAVID JOHN;MUNNS, GORDON RICHARD;FORRESTER, JULIE;STANDEN, MICHAEL CHARLES HENRY;WORTHINGTON, PAUL ANTHONY;JONES, RAYMOND VINCENT HEAVON
分类号 C07D213/64;(IPC1-7):C07D213/64;C07D213/69;C07D213/70;C07D213/84 主分类号 C07D213/64
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