发明名称 CATALYST FOR OLEFIN POLYMERIZATION AND PRODUCTION OF POLYOLEFIN
摘要 PROBLEM TO BE SOLVED: To obtain a catalyst that gives a polyolefin having a high molecular weight with a high activity at an industrially practical reaction temperature by constituting it of a divalent organic rare earth metal complex and a compound selected between an organic lithium and an organic magnesium. SOLUTION: A catalyst is constituted of a divalent organic rare earth metal complex being an organometallic compound consisting of three components of an element selected from scandium, yttrium and the lanthanide series of the periodic table, a ligand selected from cyclopentadiene derivatives and a Lewis base component, preferably a bis(pentamethyl cyclopentadienyl) samarium bis(tetrahydrofuranate), and one or more compounds selected between an organic lithium and an organic magnesium, preferably butylethyl magnesium or normal butyllithium. The catalyst is preferably used for polymerization of ethylene alone or copolymerization of ethylene with anotherα-olefin.
申请公布号 JPH11343305(A) 申请公布日期 1999.12.14
申请号 JP19980152670 申请日期 1998.06.02
申请人 NIPPON POLYOLEFIN KK 发明人 KIBINO NOBUYUKI;YAMAMOTO MASAKAZU;YASUDA HAJIME
分类号 C08F4/48;C08F4/50;C08F4/52;C08F10/00;(IPC1-7):C08F4/52 主分类号 C08F4/48
代理机构 代理人
主权项
地址