发明名称 Preparation of pure cis isomers of alpha-bis-oximes
摘要 The process for preparing substantially pure cis a-bis-oxime isomer of the formula (Ia): R1O-N=CR2-CR3=N-OR4 {wherein R1O- and R2 are in the cis configuration with respect to the N=C bond; R1 is a C-organic radical; R2 is an organic group, which may be bound directly or via an oxygen, sulphur or nitrogen atom to the main chain; R3 is hydrogen, cyano, nitro, hydroxy, amino, halogen, alkyl, haloalkyl, alkoxy, haloalkoxy, alkylthio, alkylamino, dialkylamino or cycloalkyl and R4 are hydrogen} comprises: treating a mixture of the cis and trans isomers of the a-bis-oxime isomer of the formula Ia as defined above with a Lewis acid in an aliphatic or aromatic hydrocarbon solvent is claimed.
申请公布号 NZ305363(A) 申请公布日期 1999.11.29
申请号 NZ19960305363 申请日期 1996.03.25
申请人 BASF AKTIENGESELLSCHAFT 发明人 MULLER, RUTH;BENOIT, REMY;BAYER, HERBERT;GOTZ, NORBERT;SAUTER, HUBERT
分类号 C07D231/12;C07B61/00;C07C249/04;C07C249/12;C07C249/14;C07C251/38;C07C251/48;C07C255/62;C07D261/08;(IPC1-7):C07C249/14 主分类号 C07D231/12
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