| 摘要 |
PROBLEM TO BE SOLVED: To form an image almost free from cyan fog by using a ferric complex salt of a biodegradable compd. and a dicarboxylic acid compd. SOLUTION: A photographic sensitive material having a yellow forming photosensitive silver halide emulsion layer, a magenta forming photosensitive silver halide emulsion layer, a cyan forming photosensitive silver halide emulsion layer and a nonphotosensitive hydrophilic colloidal layer on the substrate and contg. a cyan dye forming coupler selected from compds. represented by formula I in the cyan forming photosensitive silver halide emulsion layer is exposed, color-developed and processed with a processing soln. contg. a ferric complex salt of a compd. represented by formula II, III or the like and a dicarboxylic acid compd. different from the compd. forming the ferric complex salt. In the formulae, each of Z<a> and Z<b> is -N=, each of R<1> and R<2> is an electron withdrawing group having a Hammett's substituent constantσ of >=0.20, each of R', X, R1 , M<1> , M<2> , R21 -R24 , M<21> -M<24> , X1 and X2 is H or the like, each of L1 and L2 is alkylene, each of (t) and (u) is 0-3 and W is a C-contg. divalent combining group.
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