摘要 |
A positive electrode for use in alkaline rechargeable electrochemical cells comprising: a material comprising a compositionally and structurally disordered multiphase nickel hydroxide host matrix which includes at least one modifier. A process for forming a high loading uniformly distributed multiphase substantially nitrate free sintered positive electrode for use in an alkaline rechargeable electrochemical cell, the process comprising: (1) fabricating sintered electrode material by forming a slurry of nickel powder, water, carboxy methyl cellulose binder, methyl cellulose binder, and a poly(ethylene oxide) polymer; spreading the slurry on a preoxidized perforated nickel substrate; drying the slurry; and sintering the slurry; (2) impregnating the sintered electrode material using multiple impregnation cycles to attain high loading; and (3) forming the impregnated sinter into positive electrode material by presoaking the impregnated sinter in NaOH presoak tanks to substantially eliminate nitrates; brushing the presoaked impregnated sinter in a surface brushing station; charging the brushed impregnated sinter; discharging the charged impregnated sinter; rinsing the discharged impregnated sinter; and drying the rinsed impregnated sinter to complete the formation of positive electrode material. |
申请人 |
OVONIC BATTERY CO., TROY, MICH., US |
发明人 |
OVSHINSKY, STANFORD, R., BLOOMFIELD HILLS, MI 48013, US;FETCENKO, MICHAEL, A., ROCHESTER HILLS, MI 48307, US;VENKATESAN, SRINIVASAN, SOUTHFIELD, MI 48076, US;HOLLAND, ARTHUR, BLOOMFIELD HILLS, MI 48304, US |