发明名称 DIHYDROXYDIAMINO COMPOUND AND ITS PRODUCTION
摘要 PROBLEM TO BE SOLVED: To obtain the subject new compound having a specific side chain substituent group, useful as a monomer aromatic condensed polymers excellent in solubility to solvent and photosensitivity. SOLUTION: This compound is represented by formula I [(n) is 0 or 1; R and R' are each phenyl, biphenyl, etc.], e.g. 3,3'-diamino-4,4'-bis(4- hydroxyphenoxy)benzophenone. The compound of formula I is obtained by condensing 1 equivalent dihalogenodinitro compound of formula II (X is a halogen) (e.g. 3,3'-dinitro-4,4'-dichlorobenzophenone) with >=2 and preferably <=2.5 equivalent hydroxymonobenzyl ether compound of formula III (R" is the same as R and/or R') (e.g. hydroquinone monobenzyl ether) in an aprotic polar solvent (e.g. N,N-dimethylformamide) at a room temperature to 150 deg.C, preferably 40-80 deg.C and reducing the resultant dinitro compound with hydrogen.
申请公布号 JPH10316637(A) 申请公布日期 1998.12.02
申请号 JP19970125883 申请日期 1997.05.15
申请人 MITSUI CHEM INC 发明人 YAMASHITA WATARU;YOSHIMURA TOMOMI;SHIBUYA ATSUSHI;SAKATA YOSHIHIRO;OIKAWA HIDEAKI;OTA MASAHIRO
分类号 B01J23/44;C07B61/00;C07C201/12;C07C205/45;C07C221/00;C07C225/22;C07C315/04;C07C317/22;C07C319/20;C07C323/20 主分类号 B01J23/44
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