发明名称 PRODUCTION OF CARBONATE
摘要 PROBLEM TO BE SOLVED: To stably produce the subject compound without causing corrosion trouble and requiring troublesome catalyst-separating operation by carrying vapor phase reaction by using a solid catalyst as a catalyst. SOLUTION: A carbonate represented by formula I (R<1> and R<2> are each an alkyl) is subjected to transesterification reaction with a monohydric alcohol represented by the formula R<3> -OH (R<3> is an alkyl different from R<1> and R<2> ), normally in 0.1-50, preferably 0.5-20 molar ratio (of alcohol/carbonate) at 100-500 deg.C, preferably 120-300 deg.C and 10-10,000 hr<-1> , preferably 100-5,000 hr<-1> raw material gas charging space velocity(SV), generally at normal pressures by using a solid catalyst (preferably active carbon or silicate) as a catalyst to provide the objective compound represented by formula II to formula IV.
申请公布号 JPH10316628(A) 申请公布日期 1998.12.02
申请号 JP19970128403 申请日期 1997.05.19
申请人 DAICEL CHEM IND LTD 发明人 MATSUOKA KAZUYUKI
分类号 B01J27/232;C07B61/00;C07C68/06;C07C69/96 主分类号 B01J27/232
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