发明名称 |
Method for the preparation of a N-alkoxy-(tetra-or hexahydro)-phthalimide and method for the preparation of a N-alkoxyamine |
摘要 |
Method for the preparation of N-alkoxy-(tetra- or hexahydro)-phthalimide according to formula I <IMAGE> I R1 being methyl or ethyl and R2 and R3 being each independently of one another hydrogen or alkyl with 1-4 C atoms or R2 and R3 together with the carbon atom to which they are bonded forming a ring with 5 or 6 C atoms, wherein the salt of the corresponding N-hydroxy-(tetrahydro- or hexahydro)-phthalimide according to formula II: <IMAGE> II with R2 and R3 as defined above and M being an alkali metal, is brought into contact with R1Cl as alkylating agent, wherein R1 has the aforementioned meaning. The N-alkoxy-(tetra- or hexahydro)-phthalimide can afterwards be converted with the aid of hydroxylamine sulphate into the corresponding alkoxyamine after which the alkoxyamine obtained can be isolated. In this manner a simple and commercially attractive process for the preparation of O-(m)ethylhydroxylamine can be implemented.
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申请公布号 |
US5824804(A) |
申请公布日期 |
1998.10.20 |
申请号 |
US19970928126 |
申请日期 |
1997.09.12 |
申请人 |
DSM N.V. |
发明人 |
MULDERS, JOANNES M. C. A.;CALLANT, DOMINIQUE M. C.;CASTELIJNS, ANNA M. C. F. |
分类号 |
C07D209/48;(IPC1-7):C07D209/48 |
主分类号 |
C07D209/48 |
代理机构 |
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代理人 |
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主权项 |
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地址 |
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